When referring to the Spectral Atlas, please cite our publication:
Keller-Rudek, H., Moortgat, G. K., Sander, R., and Sörensen,
R.: The MPI-Mainz UV/VIS spectral atlas of gaseous molecules of
atmospheric interest, Earth Syst. Sci. Data, 5, 365–373, (2013),
DOI: 10.5194/essd-5-365-2013
|
DATAFILE: | c-C5H9O2_Rowley(1992)_298K_210-300nm.txt |
NAME: | cyclopentylperoxy radical |
FORMULA: | c-C5H9O2 |
AUTHOR(YEAR): | Rowley(1992) |
T: | 298K |
λ: | 210-300nm |
BIBLIOGRAPHY: |
D.M. Rowley, P.D. Lightfoot, R. Lesclaux, and T.J. Wallington, "Ultraviolet absorption spectrum and self-reaction of cyclopentyl peroxy radicals",
J. Chem. Soc. Faraday Trans. 88, 1369-1376 (1992);
DOI: 10.1039/FT9928801339
|
COMMENTS: | Flash photolysis technique coupled with UV absorption spectrometry; photolysis of flowing c-C5H10/Cl2/O2/N2 mixtures Original values: Calibration against the well established methylperoxy radical spectrum, using σ(CH3O2) = 4.55 x 10-18 cm2 molecule-1 at 240 nm of F. Simon, W. Schneider, and G.K. Moortgat, "UV-absorption spectrum of the methylperoxy radical and the kinetics of its disproportionation reaction at 300 K", Int. J. Chem. Kinet. 22, 791-813 (1990); DOI: 10.1002/kin.55022080 |
|
Search cross sections
|